Skarns in the Whitehorse Copper Belt occur in both dolomitic and calcareous carbonate rocks near contacts with the diorite contact phase of the Whitehorse Batholith. The skarns are mineralogically and compositionally similar to typical copper skarns.
The bulk of sulphide mineralization is associated with retrograde alteration. Chalcopyrite and pyrite are preferentially associated with actinolite and chlorite, whereas bornite and chalcocite are preferentially associated with epidote and locally serpentine. The other important copper mineral, valleriite, is restricted to magnesian rocks and is commonly associated with phlogopite, serpentine, and chlorite. Overall, the Whitehorse system is copper-rich and sulphur-poor; iron sulphide minerals are not abundant.
Significant amounts of gold and silver have been recovered from the Whitehorse skarns. Cu, Ag, and Au metal raiots of spot sample assays can be used to discriminate among the different Whitehorse skarns. Deposits formed from relatively pure limestone appear to have low precious metal ratios. Deposits formed from more magnesian protoliths appear to be silver-rich. Deposits with the highest gold ratios appear to have formed from mixed limestone-dolostone lithology.